2-Methyl-N-o-tolylbenzamide

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2-Methyl-N-o-tolyl­benzamide

In the title compound, C(15)H(15)NO, the C-N-C(O)-C amide unit is planar (r.m.s. deviation = 0.003 Å) and subtends dihedral angles of 44.71 (5) and 43.33 (5)° with the two o-tolyl rings. These aromatic rings are inclined at 4.94 (7)° to one another. The ortho-methyl groups of the two tolyl rings are anti to one another. In the crystal structure, N-H⋯O hydrogen bonds augmented by C-H⋯π inter-act...

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N-Methyl-2-thio­cytisine

The rings of the three-ring cytisine system in the title compound [systematic name: (1R,5S)-1,2,3,4,5,6-hexa-hydro-1,5-methano-8H-pyrido[1,2-a][1,5]diazo-cine-8-thione], C(12)H(16)N(2)S, have planar [maximum deviation 0.0170 (7) Å], half-chair and chair conformations. In the crystal structure, relatively short and directional C-H⋯π inter-actions and weaker secondary C-H⋯S contacts join the mol-...

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2-Methyl-N-phenyl­benzamide

In the structure of the title compound (NP2MBA), C(14)H(13)NO, the conformation of the C-O bond is syn to the ortho-methyl substituent in the benzoyl phenyl ring, while the N-H bond is anti to the ortho-methyl substituent. The structure of NP2MBA closely resembles that of 2-chloro-N-phenyl-benzamide, with similar bond parameters. The dihedral angle between the phenyl and benzoyl rings is 88.05 ...

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Sub-cellular trafficking and functionality of 2′-O-methyl and 2′-O-methyl-phosphorothioate molecular beacons

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(N→B)-4-Methyl-3-pyrid­yl[N-methyl­imino­diacetate-O,O′,N]borane

The title compound, C(11)H(13)BN(2)O(4), has a rigid bicyclic structure due to an intra-molecular nitro-gen-boron dative bond. The B atom is in a distorted tetra-hedron environment with a B-N bond length of 1.640 (2) Å, which is in good comparison with the values in analogues compounds. In the crystal, the mol-ecules are linked by weak C-H⋯O and C-H⋯N inter-actions, forming a three-dimensional ...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809050946